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Polyolefin, PVC, EPDM, silicone: choosing on temperature and chemistry

+125 °C, +110 °C, +100 °C, 105 °C. Four published continuous limits cover this entire catalogue, and the compound sets every one of them.

The network's single materials page

Sibling sites deleted their materials sections and link here. The temperature table and the tracking mechanism are argued once against one set of datasheets, instead of four times against four.

Two questions settle the compound, in this order. What is the continuous service temperature at the surface being covered, and what is that surface made of.

Diameter comes third. Every material here is offered across overlapping sizes, so nothing is eliminated by diameter until temperature and chemistry have eliminated it first. Reverse that order and you find a grade that fits 34 mm, then find it is 15 °C short.

What the range is actually made of

The heat-shrink side is one polymer. GSC thin wall, GLC-SV vented, GDW dual wall, GMW and GHW, the GRT red build-up grade, GDLT double layer, GAT anti-tracking, the GVOT stress-control sleeve and the GSF closure tube all name crosslinked polyolefin. Wall, ratio, filler and lining separate them. Chemistry does not.

One heat-shrink part breaks that. GCT screening tube is a thermally stabilised crosslinked semi-conductive polymer, and the sheet never calls it polyolefin.

Cold shrink splits properly. GCTE is EPDM, GCTS is silicone, and the two datasheets carry identical selection charts: seven sizes 20/7 to 104/42, Lf 500 mm minimum, an 8 to 94 mm application range, copper or aluminium to 1000 sq.mm. Only the code letter and the property column differ. Both stop at 1.1 kV, and nothing in the cold-shrink range goes above it.

PVC is in the range. It does not shrink.

The company started as a PVC processor in 1979 and has moulded PVC since 1988, and vinyl parts are still published: the busbar boot and shroud to 36 kV, the wildlife shroud and the TCV terminal cap are each described as specially formulated polyvinyl chloride. All are moulded. No PVC or crosslinked-PVC shrink tube appears on any published sheet. Where PVC turns up beside a tube it is the cable jacket the accessory has to seal against, listed with XLPE, PILC and rubber. If a specification calls for crosslinked PVC tubing, this range does not answer it.

GCTE 40/16 on its core, GCTE 53/24 part recovered

Both sleeves are black, which is the colour row on the EPDM datasheet. The silicone sheet prints grey. The white spiral inside the upper sleeve is the core: pull it out and the tube recovers, with no heat and no recovery temperature to hit.

The code printed along the body is GCTE. Silicone in the identical seven sizes is coded GCTS on its own datasheet, which is the third disagreement below.

Two black cold shrink sleeves on white. The upper one is straight and full bore with a white spiral core showing at each end, printed GALA GCTE Ø 40/16. The lower one is printed GCTE Ø 53/24 and has already recovered down over its right-hand half to a narrow open tube.

The three published materials, on the axes that decide

Values are the manufacturer's own, for GMW/GHW, GCTE and GCTS. Methods sit in the tables below.

DecisionCrosslinked polyolefinEPDM (GCTE)Silicone (GCTS)
How it recoversApplied heat, 125 °C shrink temperature on GMW/GHWPull the core out, no heatPull the core out, no heat
Continuous limit-40 to +110 °C on GMW/GHW, -55 to +125 °C on GSC thin wall-40 to 105 °C-40 to 105 °C
Voltage it is written for3.3 kV on GMW, 36 kV on GHW, GDLT and GAT1.1 kV1.1 kV
Colour as publishedBlack on GMW/GHW, seven standard colours on GSCBlackGrey
Chemistry declared on the sheetHalogen free, carbon black for UV on GMW/GHWFree of chloride and sulfurFree of chloride and sulfur
What rules it outA site that will not permit a flame or a hot-work permitAnything above 1.1 kV or above 105 °CAnything above 1.1 kV, and the lowest tensile of the three at 6.0 MPa

Measured properties, as published

PropertyCrosslinked polyolefin (GMW/GHW)EPDM (GCTE)Silicone (GCTS)Test method
Tensile strength12 N/mm² (min.)9.6 MPa ultimate6.0 MPa (min.)ASTM D638; ASTM D-412 for the rubbers
Ultimate elongation350% (min.)750%400% (min.)ASTM D638; ASTM D-412 for the rubbers
Hardness45 ± 10 Shore Dnot on the sheet40 ± 10 Shore AASTM D2240
Tear strengthnot on the sheet26.3 kN/m, Die C25.0 kN/m (min.)ASTM D-624C; ASTM D-624
Density1.0 ± 0.2 gm/cm³not on the sheetnot on the sheetASTM D792
Water or moisture absorption0.5% (max.)1.8% weight gain, 7 days at 90 °Cnot on the sheetASTM D570; internal method for EPDM
Fungus resistancenot on the sheet28 days exposure, no growth28 days exposure, no growthASTM G-21
Continuous temperature limit-40 °C to +110 °C-40 °C to 105 °C-40 °C to 105 °CIEC 216; no method printed on either rubber sheet
Shrink temperature125 °Cnone, recovery is mechanicalnone, recovery is mechanicalIEC 216
Dielectric strength12 kV/mm (min.) at a 2 mm wall14.3 kV/mm18.0 kV/mm (min.)ASTM D149
Volume resistivity1 × 10¹² Ohm.cm (min.)not on the sheet1 × 10¹² Ohm.cm (min.)ASTM D257
Water seal requirementnot on the sheetmeets ANSI C119.1meets ANSI C119.1ANSI C119.1

For GMW/GHW medium and heavy wall, GCTE cold shrink and GCTS cold shrink. "Not on the sheet" means that datasheet carries no such row; thin-wall polyolefin publishes different figures and sits in the temperature table further down.

Crosslinked polyolefin is a family name, not a specification

Three grades on this site declare the same polymer and hold the same 125 °C shrink temperature. Their electrical numbers are nowhere near each other.

GRT, the red build-up insulation, publishes 22 kV/mm against GMW/GHW's 12, and volume resistivity a hundred times higher. GAT, the non-tracking grade, sits between them on strength and gives up 10 °C of continuous limit to get a property none of the others has at all. A clause that names the polymer has specified almost nothing. Name the grade code.

One polymer name, three grades

PropertyGMW / GHWGRT (INSULTUBE Red)GAT anti-trackingTest method
Dielectric strength12 kV/mm (min.) at a 2 mm wall22 kV/mm (min.)15 kV/mm (min.)ASTM D149
Volume resistivity1 × 10¹² Ohm.cm (min.)1 × 10¹⁴ Ohm.cm (min.)1 × 10¹⁴ Ohm.cm (min.)ASTM D257
Dielectric constant5 (max.)5 (max.)5 (max.)ASTM D150
Shrink temperature125 °C125 °C125 °CIEC 216
Continuous temperature limit-40 °C to +110 °C-40 °C to +110 °C-40 °C to +100 °CIEC 216; no method printed on the GRT row
Track, erosion or flame failurenot on the sheetnot on the sheetnone up to 3.25 kV for 20 min.ASTM D2303
Technical Qualification ReportQR 1013QR 1036QR 1021manufacturer's own reference

GMW/GHW medium and heavy wall, GRT red build-up insulation, GAT anti-tracking. Every row is from the three datasheets.

Dielectric strength is not a ranking

Read that row and silicone looks like the strongest insulator here, 18.0 kV/mm against 12. The comparison is not worth making.

The figure is per millimetre and the walls are not the same. GMW/GHW's 12 is explicitly qualified at a 2 mm wall, GHW 40/12 recovers to 4.0 mm, and a cold-shrink sleeve recovers thin. What a finished wall withstands depends on the wall as much as on the figure, and the wall is usually what moved.

The method changes underneath the number too. GMW/GHW, GCTE and GCTS are all measured to ASTM D149. Thin-wall polyolefin quotes above 20 kV/mm to ASTM D2671 instead. GDLT quotes 20 kV/mm minimum on its insulating inner layer, while its semi-conductive outer layer carries no dielectric rating at all and 1 × 10³ Ohm.cm of volume resistivity. Figures from two methods do not belong in one league table.

Continuous temperature limit, series by series

SeriesMaterial as publishedContinuous limitMethod
GSC and GSC/YG thin wall, flame retardantcrosslinked polyolefin-55 °C to +125 °CIEC 216
GLC-SV vented thin wallcrosslinked polyolefin-40 °C to +125 °CIEC 216
GDW dual wall and GDWH harnesspolyolefin co-extruded over hot-melt adhesive-55 °C to +125 °C, qualified as outer wall on GDWIEC 216
GMWR and GHWR co-extrudedpolyolefin with a hot-melt adhesive lining-55 °C to +125 °C, qualified as outer wallIEC 216
GMW and GHW medium and heavy wallcrosslinked polyolefin-40 °C to +110 °CIEC 216
GRT red build-up insulationcrosslinked polyolefin-40 °C to +110 °Cno method printed beside the row
GAT and GAT HW anti-trackingnon-tracking crosslinked polyolefin-40 °C to +100 °CIEC 216
GDLT double layerco-extruded crosslinked polyolefin-40 °C to +100 °CIEC 216
GCTE cold shrinkEPDM-40 °C to 105 °Cno method printed, feature list only
GCTS cold shrinksilicone-40 °C to 105 °Cno method printed, feature list only

Read this column first. Everything else on a datasheet is negotiable against wall and size; this is not.

Three places the manufacturer's own sources disagree

The GMW/GHW product page claims a dielectric strength of 15 kV/mm; both GMW/GHW datasheets, standard and flame retardant, print 12 kV/mm minimum at a 2 mm wall to ASTM D149. The GDW dual wall sheet gives -55 °C to +85 °C in its feature list and -55 °C to +125 °C in its own table on the same page, the second figure qualified as the outer wall only — design the assembly to the lower one until it is resolved. And the silicone product page reproduces GCTE part codes while the silicone datasheet codes the identical seven sizes GCTS. Order silicone by the GCTS code or risk being quoted EPDM.

The chemistry declarations, and what each is doing there

Free of chloride and sulfur
Printed on both cold-shrink sheets. The manufacturer publishes the absence, not the reason; where a specification insists on it, the requirement usually traces to chloride stress-corrosion cracking of austenitic stainless steel. It is what lets a rubber sleeve onto stainless pipework that would reject a chloride-bearing elastomer.
Halogen free
Declared on GLC and GLC-SV, GSC, GMW and GHW, GRT and GAT. It governs what the tube emits in a fire, not how well it insulates, so it never appears in the electrical block and is easy to miss. Specify it for enclosed and public spaces where smoke and acid gas are the hazard. GSC adds flame retardant and self-extinguishing with a UL 224 VW-1 pass.
Carbon black
The GMW/GHW sheets carry a weathering line stating the material contains carbon black to protect it from UV light. That is why medium and heavy wall is standard black. Custom colours are offered on request and the sheets do not say what carries the UV package in them, so ask before putting a coloured medium-wall tube outdoors.
Water absorption
0.15% max on thin-wall polyolefin, 0.2% max on GRT, 0.5% max on GMW/GHW and GDLT, all to ASTM D570. For a buried or submerged joint this row outranks tensile strength: it is what the wall itself takes up, before any adhesive or seal is considered.
Fungus resistance
ASTM G-21, 28 days exposure with no growth, on both cold-shrink materials and on the GOBT oil barrier sleeve. Thin-wall polyolefin declares inert to MIL-I-7444 instead. Two tests, two reports, no conversion between them — which matters on tropical and coastal work, where these two lines at the foot of the sheet settle more than the electrical block above them.
Copper corrosion
Good, to ASTM D2671B, on the thin-wall grades and on the co-extruded GMWR/GHWR. It says the compound will not attack the conductor it is shrunk onto, which is why it appears on harness tubing sitting against bare tinned copper and not on the heavy-wall sheets.

Tracking and erosion, the mechanism no property row predicts

Everything tabulated above is a bulk property measured through the wall. Tracking is a surface process, and none of those numbers forecast it.

The manufacturer names the driver on the GVOT sheet: the tubing protects substrates from erosion caused by leakage current. On a contaminated outdoor surface that current runs across the wetted film and dries it unevenly into bands. Small arcs bridge the dry bands. Each arc pyrolyses a trace of polymer into carbon, carbon conducts, and every track shortens the path for the next arc. Erosion is the same energy removing material rather than carbonising it. Both finish in a flashover across a wall that still measures its full recovered thickness and still passes every figure above.

The answer is the GAT series, a non-tracking crosslinked polyolefin for medium-voltage joints and terminations to 36 kV. Unlike the rest of the tube range it carries a tracking row, and the method is ASTM D2303: no track, erosion or flame failure up to 3.25 kV for 20 minutes. The same line appears on the anti-tracking cable breakout, the rain sheds and the creepage extension skirt in the same compound. Quote it by name, because no other property on the sheet substitutes for it and neither does more wall. The part is on anti-tracking tube.

Which material each series actually is

SeriesMaterial as publishedCovered on
GLC, GLC-SV, GSC, GSC/YG, GLC3crosslinked polyolefinThin wall tube
GMW, GHWcrosslinked polyolefinMedium and heavy wall
GRT, GRT HW, GRT EHWcrosslinked polyolefinMedium and heavy wall
GDW, GDWHpolyolefin co-extruded over hot-melt adhesiveDual wall tube
GMWR, GHWRpolyolefin with a hot-melt adhesive liningPipe and joint sealing
GMW 5xcrosslinked polyolefin5:1 tube
GDLTco-extruded crosslinked polyolefin, insulating inner and semi-conductive outerScreening tube
GCTthermally stabilised crosslinked semi-conductive polymerScreening tube
GVOTcrosslinked polyolefin with an integrated varistor stress-control systemScreening tube
GAT, GAT HWnon-tracking crosslinked polyolefinAnti-tracking tube
GSFcrosslinked polyolefinFibre and CATV tube
GCTEEPDMCold shrink tubing
GCTSsiliconeCold shrink tubing

Send the temperature and the substrate

A material question closes in one email when it carries four things: continuous service temperature, what the tube sits against, voltage class, and whether the site permits a naked flame.